Transferring files over Wi-Fi Direct within the Samsung device family is an easy seamless process.
First you need to set up the Wi-Fi Direct connections. Here we first connect the Samsung Galaxy S6 Edge with the Samsung Galaxy S5.
We then have the Samsung Note II initiate a request to Wi-Fi Direct connect to the Samsung Galaxy S6 Edge and accept this request on the Galaxy S6 Edge.
Now all 3 Samsung devices are connected to each other over Wi-Fi Direct.
From here, it's easy to send files simultaneously from one device to the other 2 devices over Wi-Fi Direct.'
Overall Samsung has done a good job at implementing Wi-Fi Direct to share files between other Samsung devices. However, if you are trying to share files between a Samsung device and a non-Samsung device, most likely you will run into problems.